Mercury contamination poses a significant threat to the environment and human health due to its persistence, bioaccumulation, and toxicity. Conventional remediation methods such as chemical precipitation, coagulation, and membrane filtration often fall short due to limitations like incomplete removal, secondary pollution, and low selectivity. In response, advanced nanomaterials, defined as engineered nanostructures with high surface area, tunable surface chemistry, and exceptional mercury-binding capabilities, have emerged as powerful alternatives. This review critically evaluates five major classes of nanomaterials, such as carbon-based nanomaterials, metal and metal oxide nanoparticles, functionalized polymer nanocomposites, biosynthesized nanoparticles, and hybrid nanomaterials, with a focus on their mercury removal efficiency, regeneration capacity, environmental safety, and real-world applicability. While these materials have been previously reported, this work offers a unique comparative analysis that synthesizes fragmented data across the literature to highlight performance trade-offs and implementation feasibility. Furthermore, nanotechnology-assisted techniques including adsorption, photocatalysis, membrane-based separation, and hybrid treatment systems are systematically reviewed, emphasizing removal efficiencies, operational parameters, and scalability. Among these, hybrid nanomaterials and multifunctional systems demonstrate the highest potential, achieving mercury removal rates exceeding 95 % and offering adaptability to complex contaminated matrices. Rather than introducing new experimental data, this review identifies key research gaps, unresolved challenges such as nanoparticle toxicity and recovery, and the lack of field-scale validation. It concludes with a roadmap to guide future research toward the development of safe, cost-effective, and environmentally sustainable nanotechnology-driven mercury remediation strategies. This work aims to support informed decision-making among researchers, engineers, and environmental policymakers working to mitigate mercury pollution effectively.

Clustered regularly interspaced short palindromic repeats (CRISPR)/Cas12a-powered biosensor with a G-quadruplex (G4) reporter offer the benefits of simplicity and sensitivity, making them extensively utilized in detection applications. However, these biosensors used for monitoring pollutants in environmental water samples may face the problem of high background signal and easy interference due to the "signal-off" output. It is obvious that a biosensor based on the CRISPR/Cas12a system and G4 with a "signal on" output mode needs to be designed for detecting environmental pollutants.

By using phosphorothioate-modified G4 as a reporter and catalytic hairpin assembly (CHA) integrated with Cas12a as an amplification strategy, a "signal-on" colorimetric/photothermal biosensor (psG4-CHA/Cas) for portable detection of environmental pollutants was developed. With the help of functional nucleotides, the target pollutant (kanamycin or Pb2+) triggers a CHA reaction to produce numerous double-strand DNA, which can activate Cas12a's trans-cleavage activity. The active Cas12a cleaves locked DNA to release caged psG-rich sequences. Upon binding hemin, the psG-rich sequence forms a psG4/hemin complex, facilitating the oxidation of the colorless 3,3',5,5'-tetramethylbenzidine (TMB) into the blue photothermal agent (oxTMB). The smartphone was employed for portable colorimetric detection of kanamycin and Pb2+. The detection limits were found to be 100 pM for kanamycin and 50 pM for Pb2+. Detection of kanamycin and Pb2+ was also carried out using a portable thermometer with a detection limit of 10 pM for kanamycin and 8 pM for Pb2+.

Sensitive, selective, simple and robust detection of kanamycin and Pb2+ in environmental water samples is achieved with the psG4-CHA/Cas system. This system not only provides a new perspective on the development of efficient CRISPR/Cas12a-based "signal-on" designs, but also has a promising application for safeguarding human health and environmental monitoring.

Calcium (Ca2+) and phosphorous (PO43-) significantly influence the form and effectiveness of nitrogen (N), however, the precise mechanisms governing the adsorption of ammonium nitrogen (NH4+-N) and nitrate nitrogen (NO3--N) are still lacking. This study employed batch adsorption experiments, charge distribution and multi-site complexation (CD-MUSIC) models and density functional theory (DFT) calculations to elucidate the mechanism by which Ca2+ and PO43- affect the adsorption of NH4+-N and NO3--N on the goethite (GT) surface. The results showed that the adsorption of NH4+-N on the GT exhibited an initial increase followed by a decrease as pH increased, peaking at a pH of 8.5. Conversely, the adsorption of NO3--N decreased with rising pH. According to the CD-MUSIC model, Ca2+ minimally affected the NH4+-N adsorption on the GT but enhanced NO3--N adsorption via electrostatic interaction, promoting the adsorption of ≡FeOH-NO3- and ≡Fe3O-NO3- species. Similarly, PO43- inhibited the adsorption of ≡FeOH-NO3- and ≡Fe3O-NO3- species. However, PO43- boosted NH4+-N adsorption by facilitating the formation of ≡Fe3O-NH4+ via electrostatic interaction and site competition. DFT calculations indicates that although bidentate phosphate (BP) was beneficial to stabilize NH4+-N than monodentate phosphate (SP), SP-NH4+ was the main adsorption configuration at pH 5.5-9.5 owing the prevalence of SP on the GT surface under site competition of NH4+-N. The results of CD-MUSIC model and DFT calculation were verified mutually, and provide novel insights into the mechanisms underlying N fixation and migration in soil.

Recently, the utilization of metal halide perovskites in sensing and their application in environmental studies have reached a new height. Among the different metal halide perovskites, cesium lead halide perovskites (CsPbX3; X = Cl, Br, and I) and composites have attracted great interest in sensing applications owing to their exceptional optoelectronic properties. Most CsPbX3 nanostructures and composites possess great structural stability, luminescence, and electrical properties for developing distinct optical and photonic devices. When exposed to light, heat, and water, CsPbX3 and composites can display stable sensing utilities. Many CsPbX3 and composites have been reported as probes in the detection of diverse analytes, such as metal ions, anions, important chemical species, humidity, temperature, radiation photodetection, and so forth. So far, the sensing studies of metal halide perovskites covering all metallic and organic-inorganic perovskites have already been reviewed in many studies. Nevertheless, a detailed review of the sensing utilities of CsPbX3 and composites could be helpful for researchers who are looking for innovative designs using these nanomaterials. Herein, we deliver a thorough review of the sensing utilities of CsPbX3 and composites, in the quantitation of metal ions, anions, chemicals, explosives, bioanalytes, pesticides, fungicides, cellular imaging, volatile organic compounds (VOCs), toxic gases, humidity, temperature, radiation, and photodetection. Furthermore, this review also covers the synthetic pathways, design requirements, advantages, limitations, and future directions for this material.

Incidental pesticide application on farmlands can result in contamination of off-target biota, soil, groundwater, and surrounding ecosystems. To manage these pesticide contaminations sustainably, it is important to utilize advanced approaches to pesticide decontamination. This review assesses various innovative strategies applied for remediating pesticide-contaminated sites, including physical, chemical, biological, and nanoremediation. Integrated remediation approaches appear to be more effective than singular technologies. Bioremediation and chemical remediation are considered suitable and sustainable strategies for decontaminating contaminated soils. Furthermore, this study highlights key mechanisms underlying advanced pesticide remediation that have not been systematically studied. The transformation of applied pesticides into metabolites through various biotic and chemical triggering factors is well documented. Ex-situ and in-situ technologies are the two main categories employed for pesticide remediation. However, when selecting a remediation technique, it is important to consider factors such as application sites, cost-effectiveness, and specific purpose. In this review, the sustainability of existing pesticide remediation strategies is thoroughly analyzed as a pioneering effort. Additionally, the study summarizes research uncertainties and technical challenges associated with different remediation approaches. Lastly, specific recommendations and policy advocacy are suggested to enhance contemporary remediation approaches for cleaning up pesticide-contaminated sites.

Industrial wastewater is causing serious health problems due to presence of large concentrations of toxic metals. Removal of these metals is still a big challenge using pristine natural biopolymers due to their low surface area, water solubility, and poor recovery. Developing biopolymeric composites with other materials has attained attention because they possess a high surface area and structural porosity, high reactivity, and less water solubility. In simple words, biopolymeric nanohybrids have great adsorption capacity for heavy metals. Biopolymeric materials are abundant, low cost, biodegradable, and possess different functional moieties (carboxyl, amine, hydroxyl, and carbonyl) which play a vital role to adsorb metal ions through various inter-linkages (i.e., electrostatic, hydrogen bonding, ion exchange, chelation, etc.). Biopolymeric nanohybrids have been proven a potent tool in environmental remediation such as the abatement of heavy metal ions from polluted water. Herein, we have reported the adsorption potential of various biopolymers (cellulose, chitosan, pectin, gelatin, and silk proteins) for the removal of heavy metals. This review discusses the suitability of biopolymeric nanohybrids as an adsorbent for heavy metals, their synthesis, modification, adsorption potential, and adsorption mechanism along with best fitted thermodynamic and kinetic models. The influence of pH, contact time, and adsorbent dose on adsorption potential has also been discussed in detail. Lastly, the challenges, research gaps and recommendations have been presented. This review concludes that biopolymers in combination with other materials such as metal-based nanoparticles, clay, and carbon-based materials are excellent materials to remove metallic ions from wastewater. Significant adsorption of heavy metals was obtained at a moderate pH (5-6). Contact time and adsorbent dose also affect the adsorption of heavy metals in certain ways. The Pseudo-first order model fits the data for the initial period of the first step of the reaction. Kinetic studies of different adsorption processes of various biopolymeric nanohybrids described that for majority of bionanohybrids, Pseudo-second order fitted the experimental data very well. Functionalized biopolymeric nanohybrids being biodegradable, environment friendly, cost-effective materials have great potential to adsorb heavy metal ions. These may be the future materials for environmental remediation.

This article discusses the unique properties and performance of carbon-based molecularly-imprinted polymers (MIPs) for detecting hazardous pollutants in aqueous solutions. Although MIPs have several advantages such as specific recognition sites, selectivity, and stability, they suffer from a series of drawbacks, including loss of conductivity, electrocatalytic activity, and cost, which limit their use in various fields. Carbon-based MIPs, which utilize carbon electrodes, carbon nanoparticles, carbon dots, carbon nanotubes, and graphene substrates, have been the focus of research in recent years to enhance their properties and remove their weaknesses as much as possible. These carbon-based nanomaterials have excellent sensitivity and specificity for molecular identification. As a result, they have been widely used in various applications, such as assessing the environmental, biological, and food samples. This article examines the growth of carbon-based MIPs and their environmental applications.

Continuous incorporation of microplastics (MPs) and their fragmented residues into the ecosystem has sparked significant scientific apprehensions about persistence, a multitude of sources, and toxicity impacts on human health and aquatic entities. Overcoming this multifaceted hazard necessitates the development of novel techniques with robust efficiencies to eliminate microplastics from the environmental compartments. Coagulation, flocculation, and membrane filtration are non-destructive techniques but necessitate extra steps for microplastic degradation, whereas biological means have been confirmed less efficient (less than 15% degradation). Recent reports have emphasized advanced oxidation processes (AOPs) as practical treatment alternatives, representing superior catalytic efficacy for microplastic degradation (≈30-95%). Nevertheless, additional investigations should be carried out to evaluate the performance of AOPs in degrading microplastics under real environmental matrices. Moreover, the detection of transformed metabolites, degradation mechanistic insights, and toxicity bioassays are required to substantiate AOP assumption as feasible remediation substitutes. This review focuses on the source, occurrence, discharge, transportation, and associated paramount health risks of microplastics. Advanced oxidation processes-assisted removal of microplastics from the aqueous matrices is thoroughly vetted with up-to-date findings. Factors affecting the degradation of MPs have been discussed in detail. In addition to the generalized mechanistic insights into photocatalytic degradation, the risk assessment of aging intermediates is also comprehended. Finally, the review was concluded by emphasizing current research gaps and incoming research tendencies to provide guidelines for efficiently addressing microplastic pollution.