The consumption of tea, one of the most popular non-alcoholic beverages, has steadily increased, leading to a significant rise in global tea production and consequently the generation of substantial amounts of tea waste annually. China alone generates more than 5 million tons of tea waste annually, comprising trimmed stems, discarded leaves and buds, waste from the manufacturing process, and residue after brewing. Tea is rich in polyphenols, polysaccharides, amino acids, alkaloids, and other active substances. Leveraging substantial quantities of tea waste can produce cost-effective derivatives across various sectors, thereby enhancing its utilitarian value and promoting a circular economy, for "Waste to Treasure". This study aims to evaluate the potential for resourceful utilization of tea waste in diverse applications. The current state of research concerning various applications of tea waste, including its use in biochar, composting feedstock, sludge performance modifiers, disinfection and biocides, as well as animal feed is comprehensively summarized. Focusing on the preparation and application of tea-waste-derived biochar (TWB), this study identifies several limitations in current TWB production technologies, including challenges related to performance, yield, and economic viability. Combined with bibliometric analysis, machine learning methods have emerged as valuable tools for evaluating and predicting biochar performance, as well as optimizing the biochar production process. An economic assessment of TWB production costs revealed that its production cost ($434.2/ton) is lower than that of corn stover ($454.19/ton) and wheat straw ($448.01/ton), but higher than rice straw ($425.73/ton). Furthermore, the analysis highlighted pyrolysis time and heating rate as critical factors influencing production costs, offering new insights compared to prior studies. This paper summarizes the progress and challenges faced by tea wastes in the field of biochar and looks at future directions. Results will provide sustainable utilization of tea waste and assist in exploiting this abundant and cheap waste biomass in many ways.

Hexavalent chromium (Cr(VI)) contamination in soil presents significant risks due to its high toxicity to both the environment and human health. Renewable, low-cost natural materials offer promising solutions for Cr(VI) reduction and soil remediation. However, the effects of unmodified tea leaves and tea-derived biochar on chromium-contaminated soils remain inadequately understood. In this study, tea tree pruning waste was converted into biochar at various temperatures, and the impacts of both unmodified tea leaves and tea biochar on soil Cr(VI) content, chromium fractionation, and soil biochemical properties were assessed using a soil incubation experiment. The results showed that the combined treatment of tea and tea biochar produced at 500 °C reduced Cr(VI) content by up to 49.30% compared to the control. Chromium fractionation analysis revealed a significant increase in the residual chromium fraction, accounting for 32.97% of total chromium, substantially reducing its bioavailability and mobility. Soil properties were markedly improved, with notable increases in pH (14.89%), cation exchange capacity (CEC; up to 100.24%), and organic matter content (up to 167.12%) under the combined treatments. Correlation analysis confirmed that Cr(VI) content reductions were positively correlated with increases in pH, nutrient retention, and enzyme activities, highlighting their role in chromium stabilization. This study underscores the synergistic potential of unmodified tea leaves and tea biochar as an innovative, eco-friendly strategy for Cr(VI) remediation, enhancing both soil quality and heavy metal stabilization.

In this experiment, the prepared tea biochar-cellulose@LDH material (TB-CL@LDH) was combined with mycelium pellets to form the composite mycelial pellets (CMP), then assembled and immobilized with strains Pseudomonas sp. Y1 and Cupriavidus sp. ZY7 to construct a bioreactor. At the best operating parameters, the initial concentrations of phosphate (PO43--P), ammonia nitrogen (NH4+-N), chemical oxygen demand (COD), zinc (Zn2+), and phenol were 22.3, 25.0, 763.8, 1.0, and 1.0 mg L-1, the corresponding removal efficiencies were 80.4, 87.0, 83.4, 91.8, and 96.6%, respectively. Various characterization analyses demonstrated that the strain Y1 used the additional carbon source produced by the strain ZY7 degradation of cellulose to enhance the removal of composite pollutants and clarified the principle of Zn2+ and PO43--P removal by adsorption, co-precipitation and biomineralization. Pseudomonas and Cupriavidus were the dominant genera according to the high-throughput sequencing. As shown by KEGG results, nitrification and denitrification genes were affected by phenol. The study offers prospects for the simultaneous removal of complex pollutants consisting of NH4+-N, PO43--P, Zn2+, and phenol.

Herein, we have reported a photocatalytic Bi5O7I, protonated g-C3N4 heterojunction with directional charge transfer channels provided by tea waste biochar to achieve effective e-/h+ pair isolation for the improved degradation of Methylene blue (MB) and Doxycycline hydrochloride (DCHCl). An S-scheme heterojunction was fabricated via the novel method that combined hydrothermal and ultrasonic dispersion, followed by an electrostatic self-assembly route. The as-fabricated Bi5O7I/protonated g-C3N4/Tea waste biochar heterojunction formed a strong contact at the interface, as supported by the electron microscopic results. As per the adsorption and photocatalytic degradation kinetics study, Bi5O7I/Tea waste biochar/protonated g-C3N4 (40 wt%) heterojunction showed a higher adsorption rate of 41.56% and 32% for MB and DCHCl within 30 min in the dark. Also, 92.02% MB and 90.21% DCHCl degradation rates in 60 and 90 min, respectively, are approximately 43 and 32 times higher than bare Bi5O7I and protonated g-C3N4 photocatalysts. The highest adsorption and degradation rate was achieved owing to the addition of Tea waste biochar and protonated g-C3N4 in a controlled ratio, and the sufficient interfacial contact between Bi5O7I and protonated g-C3N4 is for the improved isolation rate of e-/h+ pairs as evidenced by zeta potential values photoluminescence spectra as well as from scanning and transmission electron microscopy. Moreover, Bi5O7I/Tea waste biochar/protonated g-C3N4 (40 wt%) possessed high stability and recyclability after four consecutive cycles without much altering the degradation ability. Therefore, we believe that the as-fabricated Bi5O7I/Tea waste biochar/protonated g-C3N4 (40 wt%) provides new insight into the highly efficient S-scheme mechanisms significant for accelerating multicomponent photocatalytic redox reactions; while forming an effective visible light responsive candidate for treating wastewater.

The rising consumption of the popular non-alcoholic beverage tea and its derivative products caused massive growth in worldwide tea production in the last decade, leading to the generation of huge quantities of waste tea residues every year. Most of these wastes are usually burnt or disposed in landfills without proper treatment which results in serious environmental issues by polluting water, air and soil. In the recent times, 'waste to wealth' is a fast-growing concept for environment friendly sustainable development. Utilization of the large amount of tea wastes for the production of low-cost adsorbents to reduce the expenses of water and wastewater treatment can be a sustainable way of management of these wastes which at the same time will improve circular economy also. This review endeavours to evaluate the potential of both raw and modified tea wastes towards the adsorption of pollutants from wastewater. The production of various adsorptive materials such as biochar, activated carbon, nanocomposites, hydrogels, nanoparticles from tea wastes are summarized. The advancements in their applications for the removal of different emerging contaminants from wastewater as well as potable water, air and soil are exhaustively reviewed. The outcome of the present review reveals that tea waste and its derivatives are appropriate candidates to be used as adsorbents that show tremendous effectiveness in cleaning the environment. This article will provide the readers with an in-depth knowledge on the sustainable utilization of tea waste as adsorbent materials and will assist them to explore this abundant cheap waste biomass for environmental remediation.

Porous carbon monoliths (PCMs) were prepared from waste corrugated cardboard box (WCCB) via slurrying in FeCl₃ solution followed by molding and thermal treatment. The thermal process was analyzed by a thermogravimetric analyzer coupled with a Fourier transform infrared spectrometer. The evolution of physicochemical characteristics of PCMs was studied. The photothermal conversion and solar steam generation performances of the optimal sample (PCM_Fe/600) were evaluated. The adsorption properties of PCM_Fe/600 for methylene blue (MB) were investigated. Results showed that Fe³⁺ promoted the breaking of cellulose chains in WCCB, leading to the occurrence of pyrolysis of WCCB at lower temperatures and the reduction of activation energy by 76.63 kJ mol^-1. Char yield raised because volatile radicals were captured by FeCl₃-derived amorphous Fe(III) species, then involved in char formation. Amorphous Fe(III) continuously converted into Fe₃O₄ crystallites with carbonization temperature increasing from 400 to 700 °C, then α-Fe was formed at 800 °C via the carbothermal reduction of Fe₃O₄. FeCl₃ was favorable to the formation of a developed microporous structure. Surface area significantly increased with carbonization temperature increasing from 400 to 600 °C due to the removal of volatiles. The etching of carbon by Fe₃O₄ above 700 °C also led to the increase of surface area. PCM_Fe/600 exhibited higher optical absorption than other samples due to its high graphite degree and porosity. It also had excellent photothermal performance; thus, solar steam yield was 1.46 times that of the pure water with the assistance of PCM_Fe/600. PCM_Fe/600 in floating state was effective in adsorption of MB from water. Besides, the adsorption behavior fitted Langmuir model with a monolayer adsorption capacity reached up to 70.9 mg g^-1.