|
1
|
Yılmaz Dikmen B, Sözcü A, İpek A. Application of ozone during incubation period: hatchability, chick quality and organ growth, bacterial load of feces, and first-week performance in broilers. Vet Res Commun 2025; 49:133. [PMID: 40056313 PMCID: PMC11890230 DOI: 10.1007/s11259-025-10702-2] [Citation(s) in RCA: 0] [Impact Index Per Article: 0] [Reference Citation Analysis] [Abstract] [Key Words] [MESH Headings] [Grants] [Track Full Text] [Download PDF] [Figures] [Journal Information] [Subscribe] [Scholar Register] [Received: 01/08/2025] [Accepted: 03/01/2025] [Indexed: 03/10/2025]
Abstract
This study was aimed to investigate the effects of ozone (O3) treatment during incubation period (IP) on hatchability, hatch window, chick quality and organ growth, bacterial load of feces and first-week growth performance in broilers. A total of 240 hatching eggs were weighed and randomly divided into control group (O3-IP (-)) and O3 treatment (O3-IP (+)). A commercial O3 generator was placed into the setter and O3 treatment (at the level of 0.050 ppm) was applied during 1 min per hour in a cyclic period of 3 days during the 18-day incubation period. The egg weight loss between 1 and 18 days ranged with values 8.59% in O3-IP (-) and 10.63% in O3-IP (+) group. The pipping time and incubation length was determined as 500.67 h and 527.33 h in O3-IP (-) and 489.67 h and 518.33 h in O3-IP (+) respectively. The yolk sac weight was found to be higher in the O3-IP (-) group compared to the O3-IP (+). In conclusion, O3 treatment during incubation period seems to be cause an acceleration for pipping time and shortening of total incubation period, unsteady effects for chick growth and quality, inhibitory effect for bacterial growth in feces.
Collapse
Affiliation(s)
- Bilgehan Yılmaz Dikmen
- Department of Animal Science, Faculty of Agriculture, Bursa Uludağ University, Bursa, Türkiye.
| | - Arda Sözcü
- Department of Animal Science, Faculty of Agriculture, Bursa Uludağ University, Bursa, Türkiye
| | - Aydın İpek
- Department of Animal Science, Faculty of Agriculture, Bursa Uludağ University, Bursa, Türkiye
| |
Collapse
|
|
2
|
Adeiga O, Pillay K. Adsorptive Removal of Cd(II) Ions from Water by a Cheap Lignocellulosic Adsorbent and Its Reuse as a Catalyst for the Decontamination of Sulfamethoxazole. ACS OMEGA 2024; 9:38348-38358. [PMID: 39310202 PMCID: PMC11411686 DOI: 10.1021/acsomega.3c08761] [Citation(s) in RCA: 0] [Impact Index Per Article: 0] [Reference Citation Analysis] [Abstract] [Grants] [Track Full Text] [Download PDF] [Figures] [Subscribe] [Scholar Register] [Received: 11/04/2023] [Revised: 03/28/2024] [Accepted: 04/03/2024] [Indexed: 09/25/2024]
Abstract
The work reports the removal of cadmium from water by applying an efficient low-cost lignocellulosic adsorbent, rooibos tea waste. The cadmium-loaded rooibos tea waste was used for the photocatalytic abatement of sulfamethoxazole to cater to the setback of secondary pollution mostly associated with the adsorption technique. The rooibos tea waste adsorbent displayed a high removal efficiency of about 90.63% for 10 mg/L Cd(II) ions at 45 °C, 180 min agitation time, pH 7, and a dosage of 500 mg. The process of Cd(II) adsorption was endothermic and spontaneous. Also, the spent adsorbent was found to be efficient toward the photocatalytic breakdown of 10 mg/L sulfamethoxazole with a degradation efficiency of 69% after 150 min. In addition, the extent of mineralization of the sulfamethoxazole by the spent adsorbent as obtained from the total organic carbon data was found to be 53%. Therefore, based on the results obtained from this work, rooibos tea waste lends itself as a cheap, eco-friendly, easily sourced, and viable adsorbent for the removal of toxic ions like Cd(II). Also, the successful reuse of the spent adsorbent is a promising approach to cater to the major setback of secondary pollution associated with adsorption technology.
Collapse
Affiliation(s)
- Opeoluwa
I. Adeiga
- Department of Chemical Sciences, University of Johannesburg, Doornfontein 2028, South Africa
| | - Kriveshini Pillay
- Department of Chemical Sciences, University of Johannesburg, Doornfontein 2028, South Africa
| |
Collapse
|
|
3
|
Doyo AN, Kumar R, Barakat MA. Facile Synthesis of the Polyaniline@Waste Cellulosic Nanocomposite for the Efficient Decontamination of Copper(II) and Phenol from Wastewater. NANOMATERIALS (BASEL, SWITZERLAND) 2023; 13:1014. [PMID: 36985909 PMCID: PMC10059074 DOI: 10.3390/nano13061014] [Citation(s) in RCA: 0] [Impact Index Per Article: 0] [Reference Citation Analysis] [Abstract] [Key Words] [Track Full Text] [Figures] [Subscribe] [Scholar Register] [Received: 02/13/2023] [Revised: 03/08/2023] [Accepted: 03/09/2023] [Indexed: 06/18/2023]
Abstract
The existence of heavy metals and organic pollutants in wastewater is a threat to the ecosystem and a challenge for researchers to remove using common technology. Herein, a facile one-step in situ oxidative polymerization synthesis method has been used to fabricate polyaniline@waste cellulosic nanocomposite adsornt, polyaniline-embedded waste tissue paper (PANI@WTP) to remove copper(II) and phenol from the aqueous solution. The structural and surface properties of the synthesized materials were examined by XRD, FTIR, TEM, and a zeta potential analyzer. The scavenging of the Cu(II) and phenol onto the prepared materials was investigated as a function of interaction time, pollutant concentration, and solution pH. Advanced kinetics and isotherms modeling is used to explore the Cu(II) ion and phenol adsorption mechanisms. The synthesized PANI@WTP adsorbent showed a high intake capacity for Cu(II) than phenol, with the maximum calculated adsorption capacity of 605.20 and 501.23 mg g-1, respectively. The Langmuir equilibrium isotherm model is well-fitted for Cu(II) and phenol adsorption onto the PANI@WTP. The superior scavenging capability of the PANI@WTP for Cu(II) and phenol could be explained based on the host-guest interaction forces and large active sites. Moreover, the efficiency of the PANI@WTP for Cu(II) and phenol scavenging was excellent even after the five cycles of regeneration.
Collapse
|
|
4
|
Bukhari A, Javed T, Haider MN. Adsorptive exclusion of crystal violet dye from wastewater by using fish scales as an adsorbent. J DISPER SCI TECHNOL 2022. [DOI: 10.1080/01932691.2022.2059506] [Citation(s) in RCA: 0] [Impact Index Per Article: 0] [Reference Citation Analysis] [Track Full Text] [Journal Information] [Subscribe] [Scholar Register] [Indexed: 10/18/2022]
Affiliation(s)
- Attia Bukhari
- Department of Chemistry, University of Sahiwal, Sahiwal, Punjab, Pakistan
| | - Tariq Javed
- Department of Chemistry, University of Sahiwal, Sahiwal, Punjab, Pakistan
| | | |
Collapse
|
|
5
|
Adsorption of Cu (II) Ions Present in the Distilled Beverage (Sugar Cane Spirit) Using Chitosan Derived from the Shrimp Shell. Polymers (Basel) 2022; 14:polym14030573. [PMID: 35160562 PMCID: PMC8840202 DOI: 10.3390/polym14030573] [Citation(s) in RCA: 4] [Impact Index Per Article: 1.3] [Reference Citation Analysis] [Abstract] [Track Full Text] [Download PDF] [Figures] [Journal Information] [Subscribe] [Scholar Register] [Received: 11/03/2021] [Revised: 12/31/2021] [Accepted: 01/12/2022] [Indexed: 02/05/2023] Open
Abstract
Cachaça (sugar cane spirit) is a typically Brazilian distilled beverage. Copper ions can be present in craft beverages despite their acceptance in the national and international market. This study aims to evaluate the efficiency of chitosan as an adsorbent in removing copper (II) from cachaça. The structural characteristics of the obtained chitosan and the effect of adsorbed copper were evaluated by Fourier Transform Infrared Spectroscopy (ATR-FTIR), viscosimetry, X-ray diffraction (XRD), and scanning electron microscopy (SEM). The deacetylation reaction from chitin (shrimp shell) resulted in chitosan with a deacetylation degree of 88.9% (potentiometric titration) and 86.9% (FTIR), low crystallinity, and an estimated molecular weight of 162.96 kDa. The copper reduction rate was 84.09% evaluated by spectrophotometric titration and microwave-induced plasma optical emission spectrometry (MIP–OES). The amine groups of chitosan had adsorption affinity with copper ions, and the kinetic analysis showed a better fit of the data by the Elovich equation, suggesting that the chemosorption mechanism controlled the kinetic process. The results suggest that chitosan has the potential to improve the quality and safety of cachaça.
Collapse
|
|
6
|
Tamang M, Paul KK. Adsorptive treatment of phenol from aqueous solution using chitosan/calcined eggshell adsorbent: Optimization of preparation process using Taguchi statistical analysis. J INDIAN CHEM SOC 2022. [DOI: 10.1016/j.jics.2021.100251] [Citation(s) in RCA: 6] [Impact Index Per Article: 2.0] [Reference Citation Analysis] [Track Full Text] [Journal Information] [Subscribe] [Scholar Register] [Indexed: 11/27/2022]
|
|
7
|
Zou B, Zhang S, Sun P, Zhao Q, Zhang W, Zhang X, Ran L, Zhou L, Ye Z. Synthesis of a novel Poly-chloromethyl styrene chelating resin containing Tri-pyridine aniline groups and its efficient adsorption of heavy metal ions and catalytic degradation of bisphenol A. Sep Purif Technol 2021. [DOI: 10.1016/j.seppur.2021.119234] [Citation(s) in RCA: 4] [Impact Index Per Article: 1.0] [Reference Citation Analysis] [Track Full Text] [Journal Information] [Subscribe] [Scholar Register] [Indexed: 10/21/2022]
|
|
8
|
Sherino B, Abdul Halim SN, Manan NSA, Kamboh MA, Rashidi Nodeh H, Afzal S, Bibi N, Mohamad S. Synthesis of new Zn-decorated metal-organic frameworks for enhanced removal of carcinogenic textile dye: equilibrium and kinetic modeling studies. JOURNAL OF ENVIRONMENTAL SCIENCE AND HEALTH. PART A, TOXIC/HAZARDOUS SUBSTANCES & ENVIRONMENTAL ENGINEERING 2021; 56:1296-1305. [PMID: 34651564 DOI: 10.1080/10934529.2021.1987101] [Citation(s) in RCA: 0] [Impact Index Per Article: 0] [Reference Citation Analysis] [Abstract] [Key Words] [MESH Headings] [Track Full Text] [Subscribe] [Scholar Register] [Received: 11/17/2020] [Revised: 09/17/2021] [Accepted: 09/19/2021] [Indexed: 06/13/2023]
Abstract
This paper describes the synthesis and characterization of Zn2+ decorated (adipic and terephthalic acid as linkers) piperazine-based metal-organic framework (P-MOFs) and their extraction behavior toward the Chicago sky blue (CSB) dye. The formation of Zn2+-decorated P-MOFs was confirmed by FT-IR spectroscopy, energy-dispersive spectroscopy, X-ray diffraction, BET surface area analysis and TGA. Adsorption behavior of the synthesized P-MOFs was explored through solid-phase adsorption (batch method) prior to UV-Vis spectrophotometric determination. Adsorption parameters, including adsorbent dosage, pH of solution, dye concentration, and time, were optimized. Excellent percentage removal of 94% and 95% for AP-Zn-MOF and TP-Zn-MOF, respectively, was achieved at pH 7.5. Kinetics studies indicated that the synthesized adsorbents AP-Zn-MOF and TP-Zn-MOF followed the pseudo-second-order rate model with R2 value 0.9989. The Freundlich isotherm with high R2 value as compared to Langmuir isotherm indicated that CSB adsorption for the synthesized MOFs follows multilayer adsorption.
Collapse
Affiliation(s)
- Bibi Sherino
- Department of Chemistry, Faculty of Science, University Malaya, Kuala Lumpur, Malaysia
- Department of Chemistry, Sardar Bahadur Khan Women University, Quetta, Balochistan, Pakistan
| | | | - Ninie Suhana Abdul Manan
- Department of Chemistry, Faculty of Science, University Malaya, Kuala Lumpur, Malaysia
- University Malaya Centre for Ionic Liquids, University of Malaya, Kuala Lumpur, Malaysia
| | - Muhammad Afzal Kamboh
- Department of Chemistry, Shaheed Benazir Bhutto University, Shaheed Benazirabad, Sindh, Pakistan
| | - Hamid Rashidi Nodeh
- Department of Chemistry, Faculty of Science, University Malaya, Kuala Lumpur, Malaysia
- Department of Chemistry, Faculty of Science, University of Tehran, Tehran, Iran
| | - Saba Afzal
- Department of Chemistry, Faculty of Science, University Malaya, Kuala Lumpur, Malaysia
- Department of Chemistry, Sardar Bahadur Khan Women University, Quetta, Balochistan, Pakistan
| | - Nusrat Bibi
- Department of Chemistry, Sardar Bahadur Khan Women University, Quetta, Balochistan, Pakistan
| | - Sharifah Mohamad
- Department of Chemistry, Faculty of Science, University Malaya, Kuala Lumpur, Malaysia
- University Malaya Centre for Ionic Liquids, University of Malaya, Kuala Lumpur, Malaysia
| |
Collapse
|
|
9
|
Eco friendly adsorbents for removal of phenol from aqueous solution employing nanoparticle zero-valent iron synthesized from modified green tea bio-waste and supported on silty clay. Chin J Chem Eng 2021. [DOI: 10.1016/j.cjche.2020.07.031] [Citation(s) in RCA: 25] [Impact Index Per Article: 6.3] [Reference Citation Analysis] [Track Full Text] [Journal Information] [Subscribe] [Scholar Register] [Indexed: 11/30/2022]
|
|
10
|
Kınaytürk NK, Tunalı B, Türköz Altuğ D. Eggshell as a biomaterial can have a sorption capability on its surface: A spectroscopic research. ROYAL SOCIETY OPEN SCIENCE 2021; 8:210100. [PMID: 34150316 PMCID: PMC8206697 DOI: 10.1098/rsos.210100] [Citation(s) in RCA: 1] [Impact Index Per Article: 0.3] [Reference Citation Analysis] [Abstract] [Key Words] [Track Full Text] [Subscribe] [Scholar Register] [Received: 01/27/2021] [Accepted: 05/11/2021] [Indexed: 06/01/2023]
Abstract
In this study, eggshell as a biomaterial was used as an adsorbent. This natural waste material is easy to access and cost-free. The surface of the eggshell with its porous structure showed affinity to adsorb damaging chemicals. In particular insecticides cause serious environmental pollution in agriculture, and this is a general problem all over the world. The aim was to remove insecticides from the environment and monitor the pesticides on the surface of eggshells by atomic force microscopy (AFM) images, Fourier transform infrared (FTIR) and UV/Vis spectroscopic techniques. Five types of eggshells, Denizli Hen, Coturnix Coturnix Japonica, Light Brahma Chicken, Alectoris Chukar and ISA Tinted -White, were used. Since they are commonly used, Cypermethrin, Deltamethrin and Indoxacarb were chosen as insecticide samples. The interaction effect of insecticides on the surface of eggshells was determined by AFM images; it was seen that the semispherical surface structures of the eggshells were flattened after adsorption. FTIR spectroscopy was used both to detect structural analysis and to determine the adsorption influence. In addition, UV-Vis spectroscopy was performed to evaluate the adsorption and desorption process. Porous media of different types of eggshells with an aqueous solution of insecticides had an electronegativity attractive surface which makes it an ideal adsorbent via hydroxyl groups.
Collapse
Affiliation(s)
- Neslihan Kaya Kınaytürk
- Faculty of Arts and Sciences, Department of Nanoscience and Nanotechnology, Burdur Mehmet Akif Ersoy University, Burdur, Turkey
| | - Belgin Tunalı
- Faculty of Arts and Sciences, Department of Nanoscience and Nanotechnology, Burdur Mehmet Akif Ersoy University, Burdur, Turkey
| | - Deniz Türköz Altuğ
- Isparta Vocational School of Health Services, Süleyman Demirel University, East Campus, Isparta 32260, Turkey
| |
Collapse
|
|
11
|
Removal of phenylalanine from egg white powder: Two-step enzymatic method combined with activated carbon adsorption. Process Biochem 2021. [DOI: 10.1016/j.procbio.2021.03.004] [Citation(s) in RCA: 2] [Impact Index Per Article: 0.5] [Reference Citation Analysis] [Track Full Text] [Journal Information] [Submit a Manuscript] [Subscribe] [Scholar Register] [Indexed: 01/11/2023]
|
|
12
|
Bwatanglang IB, Magili ST, Kaigamma I. Adsorption of phenol over bio-based silica/calcium carbonate (CS-SiO 2/CaCO 3) nanocomposite synthesized from waste eggshells and rice husks. PEERJ PHYSICAL CHEMISTRY 2021. [DOI: 10.7717/peerj-pchem.17] [Citation(s) in RCA: 2] [Impact Index Per Article: 0.5] [Reference Citation Analysis] [Abstract] [Track Full Text] [Journal Information] [Subscribe] [Scholar Register] [Indexed: 11/20/2022] Open
Abstract
A bio-based Silica/Calcium Carbonate (CS–SiO2/CaCO3) nanocomposite was synthesized in this study using waste eggshells (ES) and rice husks (RH). The adsorbents (ESCaCO3, RHSiO2 and, CS-SiO2/CaCO3) characterized using XRD show crystallinity associated with the calcite and quartz phase. The FTIR of ESCaCO3 shows the CO−23 group of CaCO3, while the spectra of RHSiO2 majorly show the siloxane bonds (Si–O–Si) in addition to the asymmetric and symmetric bending mode of SiO2. The spectra for Chitosan (CS) show peaks corresponding to the C=O vibration mode of amides, C–N stretching, and C–O stretching. The CS–SiO2/CaCO3 nanocomposite shows the spectra pattern associated with ESCaCO3 and RHSiO2. The FESEM micrograph shows a near monodispersed and spherical CS–SiO2/CaCO3 nanocomposite morphology, with an average size distribution of 32.15 ± 6.20 nm. The corresponding EDX showed the representative peaks for Ca, C, Si, and O. The highest removal efficiency of phenol over the adsorbents was observed over CS–SiO2/CaCO3 nanocomposite compared to other adsorbents. Adsorbing 84–89% of phenol in 60–90 min at a pH of 5.4, and a dose of 0.15 g in 20 ml of 25 mg/L phenol concentration. The result of the kinetic model shows the adsorption processes to be best described by pseudo-second-order. The highest correlation coefficient (R2) of 0.99 was observed in CS-SiO2/CaCO3 nanocomposite, followed by RHSiO2 and ESCaCO3. The result shows the equilibrium data for all the adsorbents fitting well to the Langmuir isotherm model, and follow the trend CS-SiO2/CaCO3 > ESCaCO3 > RHSiO2. The Langmuir equation and Freundlich model in this study show a higher correlation coefficient (R2 = 0.9912 and 0.9905) for phenol adsorption onto the CS–SiO2/CaCO3 nanocomposite with a maximum adsorption capacity (qm ) of 14.06 mg/g compared to RHSiO2 (10.64 mg/g) and ESCaCO3 (10.33 mg/g). The results suggest good monolayer coverage on the adsorbent’s surface (Langmuir) and heterogeneous surfaces with available binding sites (Freundlich).
Collapse
|
|
13
|
Mansour RAEG, Simeda MG, Zaatout AA. Removal of brilliant green dye from synthetic wastewater under batch mode using chemically activated date pit carbon. RSC Adv 2021; 11:7851-7861. [PMID: 35423310 PMCID: PMC8695073 DOI: 10.1039/d0ra08488c] [Citation(s) in RCA: 30] [Impact Index Per Article: 7.5] [Reference Citation Analysis] [Abstract] [Track Full Text] [Download PDF] [Figures] [Journal Information] [Subscribe] [Scholar Register] [Received: 10/05/2020] [Accepted: 02/05/2021] [Indexed: 11/25/2022] Open
Abstract
In this research, a single-stage batch adsorber was designed for removal of brilliant green dye (BG) from aqueous solutions using activated carbon derived from date pits (ADPC) based on the Freundlich isotherm which was the best-fitted isotherm model. Experimental work was carried out within the range of 10-50 ppm initial dye concentration to determine the optimum operating conditions which were 55 min contact time, 0.06 g adsorbent mass, 25 °C, and pH = 8. Process kinetics was best-fitted with the pseudo-second order model, which revealed that the intra-particle diffusion stage is the rate-controlling stage for the process. The process efficiency was assessed by infrared spectroscopy (FTIR), scanning microscopy (SEM), X-ray spectroscopy (EDXS), and Brunauer-Emmett-Teller (BET) where the latter showed that the specific surface area of the adsorbent is 311.38 m2 g-1, which gives a favorable maximum monolayer adsorption capacity (77.8 mg g-1). The thermodynamic study proved that BG adsorption on ADPC was physiosorptive (ΔG = -5.86 kJ mol-1) and spontaneous at low temperature (ΔH = -17.7 kJ mol-1, ΔS = -0.04 kJ mol-1 K-1).
Collapse
Affiliation(s)
| | - Mohamed Gamal Simeda
- Chemical Engineering Department, Higher Institute of Engineering and Technology New Damietta Egypt
| | - Ahmed Amin Zaatout
- Chemical Engineering Department, Faculty of Engineering, Alexandria University Egypt
| |
Collapse
|
|
14
|
Al‐Mokhalelati K, Al‐Bakri I, Al Shibeh Al Wattar N. Adsorption of methylene blue onto sugarcane bagasse‐based adsorbent materials. J PHYS ORG CHEM 2021. [DOI: 10.1002/poc.4193] [Citation(s) in RCA: 6] [Impact Index Per Article: 1.5] [Reference Citation Analysis] [Track Full Text] [Journal Information] [Subscribe] [Scholar Register] [Indexed: 11/11/2022]
Affiliation(s)
- Kamal Al‐Mokhalelati
- Department of Chemistry, Faculty of Science University of Damascus Damascus Syria
| | - Iman Al‐Bakri
- Department of Chemistry, Faculty of Science University of Damascus Damascus Syria
| | | |
Collapse
|
|
15
|
Adsorption of lead ions from aqueous solutions by porous cellulose nanofiber–sodium alginate hydrogel beads. J Mol Liq 2021. [DOI: 10.1016/j.molliq.2020.115122] [Citation(s) in RCA: 56] [Impact Index Per Article: 14.0] [Reference Citation Analysis] [Track Full Text] [Journal Information] [Subscribe] [Scholar Register] [Indexed: 01/08/2023]
|
|
16
|
Younis AM, Elkady EM, Saleh SM. Novel eco-friendly amino-modified nanoparticles for phenol removal from aqueous solution. ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH INTERNATIONAL 2020; 27:30694-30705. [PMID: 32468377 DOI: 10.1007/s11356-020-09313-y] [Citation(s) in RCA: 2] [Impact Index Per Article: 0.4] [Reference Citation Analysis] [Abstract] [Key Words] [MESH Headings] [Track Full Text] [Subscribe] [Scholar Register] [Received: 02/13/2020] [Accepted: 05/14/2020] [Indexed: 06/11/2023]
Abstract
Herein, the impact of using dried Caulerpa prolifera nanoparticles and silica-coated Caulerpa prolifera nanoparticles for the removal of phenol from aqueous solution has been investigated. The chemical structure and morphology of both dried Caulerpa prolifera nanoparticles and silica-coated Caulerpa prolifera nanoparticles were characterized by using Fourier-transform infrared spectroscopy (FTIR), Brunauer Emmett Teller (BET), scanning electron microscopy (SEM), and transmission electron microscope (TEM). Batch mode experiments were conducted depending on adsorbent dosage, pH, contact time, and initial phenol concentration. In order to investigate the adsorption mechanism of the phenol molecules to the surface of the nanoparticles, kinetic models including pseudo-first-order, pseudo-second-order, and intra-particle diffusion models were executed. To describe the equilibrium isotherms, Langmuir and Freundlich isotherms were analyzed. However, the Langmuir isotherm model was agreed to be more significant with the obtained experimental data.
Collapse
Affiliation(s)
- Alaa M Younis
- Aquatic Environment Department, Faculty of Fish Resources, Suez University, Suez, 43518, Egypt.
| | - Eman M Elkady
- Marine Chemistry Lab, National Institute of Oceanography & Fisheries, Suez, Egypt
| | - Sayed M Saleh
- Department of Chemistry, College of Science, Qassim University, Buraidah, Saudi Arabia
- Chemistry Branch, Department of Science and Mathematics, Faculty of Petroleum and Mining Engineering, Suez University, Suez, 43721, Egypt
| |
Collapse
|
|
17
|
Abstract
Oil pollutants, due to their toxicity, mutagenicity, and carcinogenicity, are considered a serious threat to human health and the environment. Petroleum hydrocarbons compounds, for instance, benzene, toluene, ethylbenzene, xylene, are among the natural compounds of crude oil and petrol and are often found in surface and underground water as a result of industrial activities, especially the handling of petrochemicals, reservoir leakage or inappropriate waste disposal processes. Methods based on the conventional wastewater treatment processes are not able to effectively eliminate oil compounds, and the high concentrations of these pollutants, as well as active sludge, may affect the activities and normal efficiency of the refinery. The methods of removal should not involve the production of harmful secondary pollutants in addition to wastewater at the level allowed for discharge into the environment. The output of sewage filtration by coagulation and dissolved air flotation (DAF) flocculation can be transferred to a biological reactor for further purification. Advanced coagulation methods such as electrocoagulation and flocculation are more advanced than conventional physical and chemical methods, but the major disadvantages are the production of large quantities of dangerous sludge that is unrecoverable and often repelled. Physical separation methods can be used to isolate large quantities of petroleum compounds, and, in some cases, these compounds can be recycled with a number of processes. The great disadvantage of these methods is the high demand for energy and the high number of blockages and clogging of a number of tools and equipment used in this process. Third-party refinement can further meet the objective of water reuse using methods such as nano-filtration, reverse osmosis, and advanced oxidation. Adsorption is an emergency technology that can be applied using minerals and excellent materials using low-cost materials and adsorbents. By combining the adsorption process with one of the advanced methods, in addition to lower sludge production, the process cost can also be reduced.
Collapse
|
|
18
|
Fathy M, Selim H, Shahawy AEL. Chitosan/MCM-48 nanocomposite as a potential adsorbent for removing phenol from aqueous solution. RSC Adv 2020; 10:23417-23430. [PMID: 35520349 PMCID: PMC9054931 DOI: 10.1039/d0ra02960b] [Citation(s) in RCA: 16] [Impact Index Per Article: 3.2] [Reference Citation Analysis] [Abstract] [Track Full Text] [Download PDF] [Figures] [Journal Information] [Subscribe] [Scholar Register] [Received: 04/01/2020] [Accepted: 06/07/2020] [Indexed: 11/21/2022] Open
Abstract
A new hybrid mesoporous nanocomposite (CMCM-48) based on chitosan and silica MCM-48 was considered as a potential adsorbent for removing phenol from aqueous solutions (toxic liquid waste) in a batch process. The new composite adsorbent was characterized by scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), and nitrogen adsorption–desorption isotherms. The adsorption isotherm studies were analyzed using linear and nonlinear Langmuir, Freundlich and Dubinin–Radushkevich models for the optimum conditions when the initial phenol concentration, pH, adsorption temperature and time were 10–500 mg L−1, 3–10, 25.5 °C and 300 min, respectively. It was revealed that the experimental results agree well with the Dubinin–Radushkevich model, i.e. the correlation coefficient R2 was 0.983085. The adsorption kinetics was modeled with linear and nonlinear pseudo-first-order, pseudo-second-order and intra particle diffusion kinetic models. The pseudo-second-order model was the best for describing the adsorption process with a correlation coefficient R2 = 0.99925. The stability of the equilibrium data was studied for a phenol sorbent with a maximum adsorption capacity of 149.25 mg g−1. The results verified that the synthesized CMCM-48 was an efficient adsorbent for removing phenol from aqueous solutions. A new hybrid mesoporous nanocomposite (CMCM-48) based on chitosan and silica MCM-48 was considered as a potential adsorbent for removing phenol from aqueous solutions (toxic liquid waste) in a batch process.![]()
Collapse
Affiliation(s)
- Mahmoud Fathy
- Department of Petroleum Application
- Core Lab Analysis Center
- Egyptian Petroleum Research Institute
- Nasr City P.B. 11727
- Egypt
| | - Hanaa Selim
- Department of Analysis and Evaluation
- Central Lab
- Egyptian Petroleum Research Institute
- Nasr City P.B. 11727
- Egypt
| | - Abeer E. L. Shahawy
- Department of Civil Engineering
- Faculty of Engineering
- Suez Canal University
- Ismailia
- Egypt
| |
Collapse
|
|
19
|
Salari M, Dehghani MH, Azari A, Motevalli MD, Shabanloo A, Ali I. High performance removal of phenol from aqueous solution by magnetic chitosan based on response surface methodology and genetic algorithm. J Mol Liq 2019. [DOI: 10.1016/j.molliq.2019.04.065] [Citation(s) in RCA: 48] [Impact Index Per Article: 8.0] [Reference Citation Analysis] [Track Full Text] [Journal Information] [Subscribe] [Scholar Register] [Indexed: 12/11/2022]
|
|
20
|
Santos LB, de Oliveira DM, de Souza AO, Lemos VA. A new method for the speciation of arsenic species in water, seafood and cigarette samples using an eggshell membrane. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY 2019. [DOI: 10.1007/s13738-019-01665-8] [Citation(s) in RCA: 1] [Impact Index Per Article: 0.2] [Reference Citation Analysis] [Track Full Text] [Subscribe] [Scholar Register] [Indexed: 10/27/2022]
|
|
21
|
Kumar NS, Asif M, Al-Hazzaa MI. Adsorptive removal of phenolic compounds from aqueous solutions using pine cone biomass: kinetics and equilibrium studies. ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH INTERNATIONAL 2018; 25:21949-21960. [PMID: 29797196 DOI: 10.1007/s11356-018-2315-5] [Citation(s) in RCA: 10] [Impact Index Per Article: 1.4] [Reference Citation Analysis] [Abstract] [Key Words] [MESH Headings] [Track Full Text] [Subscribe] [Scholar Register] [Received: 02/15/2018] [Accepted: 05/13/2018] [Indexed: 06/08/2023]
Abstract
In this study, a novel inexpensive biosorbent of pine cone powder was used for the treatment of wastewater contaminated with phenol and chlorophenols (CPhs). The biosorbent was thoroughly characterized by using CHN and BET measurements, as well as FTIR, SEM, and XRD analyses. Kinetic and equilibrium biosorption experiments showed that the uptake was more than 80% within the first 30 min of contact time at pH 5.0. The biosorption of 4-CPh onto pine cone powder was higher than those of phenol and 2-CPh. The kinetic data were consistent with the pseudo-first-order kinetic model, and the Langmuir isotherm model best represented the equilibrium data. The maximum biosorption capacities of phenol, 2-CPh, and 4-CPh were 164.51, 189.44, and 220.12 mg/g, respectively, at 30 ± 1 °C. Therefore, the pine cone powder is an effective low-cost adsorbent for the removal of phenol and CPhs from the contaminated water.
Collapse
Affiliation(s)
- Nadavala Siva Kumar
- Department of Chemical Engineering, King Saud University, P.O. Box 800, Riyadh, 11421, Saudi Arabia.
| | - Mohammad Asif
- Department of Chemical Engineering, King Saud University, P.O. Box 800, Riyadh, 11421, Saudi Arabia
| | - Mansour I Al-Hazzaa
- Department of Chemical Engineering, King Saud University, P.O. Box 800, Riyadh, 11421, Saudi Arabia
| |
Collapse
|
|
22
|
Al-Ghouti MA, Khan M. Eggshell membrane as a novel bio sorbent for remediation of boron from desalinated water. JOURNAL OF ENVIRONMENTAL MANAGEMENT 2018; 207:405-416. [PMID: 29190483 DOI: 10.1016/j.jenvman.2017.11.062] [Citation(s) in RCA: 11] [Impact Index Per Article: 1.6] [Reference Citation Analysis] [Abstract] [Key Words] [MESH Headings] [Track Full Text] [Subscribe] [Scholar Register] [Received: 08/26/2017] [Revised: 11/24/2017] [Accepted: 11/24/2017] [Indexed: 06/07/2023]
Abstract
This study investigated the use of eggshell membrane (ESM) as a bio-sorbent and the effect of temperature, pH, and initial concentration on its efficiency. Furthermore, by altering the chemical composition, modified eggshell membrane (MESM) was prepared, and its efficiency was compared with the ESM. Results showed that the adsorption of boron preferred an acidic condition; pH 6 at 35 °C. In addition, the positive value of ΔH° suggested that the reaction favored endothermic pathway, while the negative value for ΔG° further suggested that the adsorption process was spontaneous. Furthermore, the ESM could adsorb 97% of boron, while MESM was able to adsorb 95%. From the Fourier transform infrared (FTIR), different functional groups were recorded on the surface of the ESM and MESM, and they played key role in the boron adsorption mechanisms. Linear Freundlich model was suggested to best describe the experimental data with 99.4% correlation coefficient.
Collapse
Affiliation(s)
- Mohammad A Al-Ghouti
- Department of Biological and Environmental Sciences, College of Arts and Sciences, Qatar University, Doha, P.O. Box: 2713, Qatar.
| | - Mariam Khan
- Department of Biological and Environmental Sciences, College of Arts and Sciences, Qatar University, Doha, P.O. Box: 2713, Qatar
| |
Collapse
|
|
23
|
Efficient removal of phenol from aqueous solutions using hydroxyapatite and substituted hydroxyapatites. REACTION KINETICS MECHANISMS AND CATALYSIS 2017. [DOI: 10.1007/s11144-017-1197-8] [Citation(s) in RCA: 4] [Impact Index Per Article: 0.5] [Reference Citation Analysis] [Track Full Text] [Subscribe] [Scholar Register] [Indexed: 10/19/2022]
|
|
24
|
Bai W, Fan L, Zhou Y, Zhang Y, Shi J, Lv G, Wu Y, Liu Q, Song J. Removal of Cd2+ions from aqueous solution using cassava starch-based superabsorbent polymers. J Appl Polym Sci 2017. [DOI: 10.1002/app.44758] [Citation(s) in RCA: 13] [Impact Index Per Article: 1.6] [Reference Citation Analysis] [Track Full Text] [Journal Information] [Subscribe] [Scholar Register] [Indexed: 01/30/2023]
Affiliation(s)
- Wenbo Bai
- Institute of Environment and Sustainable Development in Agriculture, Chinese Academy of Agricultural Sciences; 100081 Beijing People's Republic of China
| | - Liren Fan
- Faculty of Materials Science and Chemistry; China University of Geosciences (Wuhan); 430074 Wuhan People's Republic of China
- China Ground Golden Shield Environment Technology Co. Ltd; 430032 Wuhan People's Republic of China
| | - Yang Zhou
- China Ground Golden Shield Environment Technology Co. Ltd; 430032 Wuhan People's Republic of China
| | - Yin Zhang
- China Ground Golden Shield Environment Technology Co. Ltd; 430032 Wuhan People's Republic of China
| | - Jiyan Shi
- Faculty of Materials Science and Chemistry; China University of Geosciences (Wuhan); 430074 Wuhan People's Republic of China
| | - Guohua Lv
- Institute of Environment and Sustainable Development in Agriculture, Chinese Academy of Agricultural Sciences; 100081 Beijing People's Republic of China
| | - Yongfeng Wu
- Institute of Environment and Sustainable Development in Agriculture, Chinese Academy of Agricultural Sciences; 100081 Beijing People's Republic of China
| | - Qi Liu
- Institute of Environment and Sustainable Development in Agriculture, Chinese Academy of Agricultural Sciences; 100081 Beijing People's Republic of China
| | - Jiqing Song
- Institute of Environment and Sustainable Development in Agriculture, Chinese Academy of Agricultural Sciences; 100081 Beijing People's Republic of China
- China Ground Golden Shield Environment Technology Co. Ltd; 430032 Wuhan People's Republic of China
| |
Collapse
|
|
25
|
|
|
26
|
Ashrafi S, Kamani H, Mahvi A. The optimization study of direct red 81 and methylene blue adsorption on NaOH-modified rice husk. DESALINATION AND WATER TREATMENT 2016; 57:738-746. [DOI: 10.1080/19443994.2014.979329] [Citation(s) in RCA: 32] [Impact Index Per Article: 3.6] [Reference Citation Analysis] [Track Full Text] [Subscribe] [Scholar Register] [Indexed: 12/07/2022]
|
|
27
|
Cheng Z, Zhang L, Guo X, Jiang X, Li T. Adsorption behavior of direct red 80 and congo red onto activated carbon/surfactant: process optimization, kinetics and equilibrium. SPECTROCHIMICA ACTA. PART A, MOLECULAR AND BIOMOLECULAR SPECTROSCOPY 2015; 137:1126-1143. [PMID: 25305604 DOI: 10.1016/j.saa.2014.08.138] [Citation(s) in RCA: 42] [Impact Index Per Article: 4.2] [Reference Citation Analysis] [Abstract] [Key Words] [MESH Headings] [Track Full Text] [Subscribe] [Scholar Register] [Received: 05/02/2014] [Revised: 08/20/2014] [Accepted: 08/31/2014] [Indexed: 06/04/2023]
Abstract
Adsorptions of congo red and direct red 80 onto activated carbon/surfactant from aqueous solution were optimized. The Box-Behnken design (BBD) has been employed to analyze the effects of concentration of surfactant, temperature, pH, and initial concentration of the dye in the adsorption capacity. Their corresponding experimental data could be evaluated excellently by second order polynomial regression models and the two models were also examined based on the analysis of variance and t test statistics, respectively. The optimum conditions were obtained as follows: Cs=34.10 μM, T=50°C, pH=3.5, and CCR=160 mg/L for the congo red system, and Cs=34.10 μM, T=50°C, pH=6.1, and CDR80=110 mg/L for the direct red 80 system. And in these conditions, the measured experimental maximum adsorption capacities for the congo red and direct red 80 removals were 769.48 mg/g and 519.90 mg/g, which were consistent with their corresponding predicted values, with small relative errors of -2.81% and -0.67%, respectively. The adsorption equilibrium and kinetics for the two dye adsorptions onto AC/DDAC were also investigated. The experimental data were fitted by four isotherm models, and Langmuir model presented the best fit. The kinetic studies indicated that the kinetic data followed the pseudo-second-order model.
Collapse
Affiliation(s)
- Zhengjun Cheng
- State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation, Southwest Petroleum University, Chengdu 610500, Sichuan, China; School of Chemistry and Chemical Engineering, Southwest Petroleum University, Chengdu 610500, Sichuan, China; Chemical Synthesis and Pollution Control Key Laboratory of Sichuan Province, China West Normal University, Nanchong 637002, China.
| | - Lei Zhang
- State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation, Southwest Petroleum University, Chengdu 610500, Sichuan, China; School of Chemistry and Chemical Engineering, Southwest Petroleum University, Chengdu 610500, Sichuan, China.
| | - Xiao Guo
- State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation, Southwest Petroleum University, Chengdu 610500, Sichuan, China
| | - Xiaohui Jiang
- Chemical Synthesis and Pollution Control Key Laboratory of Sichuan Province, China West Normal University, Nanchong 637002, China
| | - Tian Li
- Chemical Synthesis and Pollution Control Key Laboratory of Sichuan Province, China West Normal University, Nanchong 637002, China
| |
Collapse
|
|
28
|
Zhou Y, Gu X, Zhang R, Lu J. Influences of Various Cyclodextrins on the Photodegradation of Phenol and Bisphenol A under UV Light. Ind Eng Chem Res 2015. [DOI: 10.1021/ie503414k] [Citation(s) in RCA: 31] [Impact Index Per Article: 3.1] [Reference Citation Analysis] [Track Full Text] [Journal Information] [Subscribe] [Scholar Register] [Indexed: 11/29/2022]
Affiliation(s)
- Yanbo Zhou
- Key Laboratory of Coal Gasification
and Energy Chemical Engineering of Ministry of Education, East China University of Science and Technology, No. 130, Meilong Road, Shanghai 200237, People’s Republic of China
| | - Xiaochen Gu
- Key Laboratory of Coal Gasification
and Energy Chemical Engineering of Ministry of Education, East China University of Science and Technology, No. 130, Meilong Road, Shanghai 200237, People’s Republic of China
| | - Ruzhuang Zhang
- Key Laboratory of Coal Gasification
and Energy Chemical Engineering of Ministry of Education, East China University of Science and Technology, No. 130, Meilong Road, Shanghai 200237, People’s Republic of China
| | - Jun Lu
- Key Laboratory of Coal Gasification
and Energy Chemical Engineering of Ministry of Education, East China University of Science and Technology, No. 130, Meilong Road, Shanghai 200237, People’s Republic of China
| |
Collapse
|